Q.41 Given below are two statements: Statement I: The chemical potential of an uncharged solute S, in a given medium can be defined as in equation μs = μ°s + RT ln a Statement II: μ°s = standard chemical potential is at 1 M concentration R = Gas constant T = Temperature a = Natural logarithm of the activity of the solvent In the light of the above statements, choose the most appropriate answer from the options given below: Both Statement I and Statement II are true Both Statement I and Statement II are false Statement I is true but Statement II is false Statement I is false but Statement II is true

Q.41 Given below are two statements:

Statement I:
The chemical potential of an uncharged solute S, in a given medium can be defined as in equation

μs = μ°s + RT ln a

Statement II:
μ°s = standard chemical potential is at 1 M concentration

R = Gas constant
T = Temperature
a = Natural logarithm of the activity of the solvent

In the light of the above statements, choose the most appropriate answer from the options given below:

  1. Both Statement I and Statement II are true
  2. Both Statement I and Statement II are false
  3. Statement I is true but Statement II is false
  4. Statement I is false but Statement II is true

    Statement I is true, but Statement II is false.

    Detailed Explanation

    Statement I: The equation μ_s = μ°_s + RT ln a correctly defines the chemical potential of an uncharged solute S. Here, μ°_s is the standard chemical potential, R is the gas constant, T is temperature, and a is the activity of the solute (often approximated by concentration or mole fraction at low concentrations). This is the standard thermodynamic expression for any species, including uncharged solutes.

    Statement II: False—μ°_s (standard chemical potential) is defined at unit activity (a = 1), not specifically “at 1 M concentration.” For solutes, unit activity corresponds to a hypothetical ideal 1 M (or 1 molal) state with zero interactions, but the definition hinges on a = 1, not concentration alone. Real 1 M solutions have activity coefficients deviating from 1.

    Options Explained

    Both true: Incorrect—Statement II misdefines standard state.

    Both false: Incorrect—Statement I is standard thermodynamics.

    Statement I true, II falseCorrect—I matches textbook equation; II confuses activity with concentration.

    Statement I false, II true: Incorrect—both parts wrong as explained.

    Introduction
    The chemical potential of an uncharged solute follows μ_s = μ°_s + RT ln a, where a is solute activity—not solvent as misstated. Standard chemical potential μ°_s occurs at unit activity (a=1), making Statement I true but II false, as it’s not strictly “1 M concentration.”

    Chemical Potential Basics

    Chemical potential (μ) drives diffusion and equilibrium: equal μ on both sides of a membrane means no net flow. For uncharged solutes, activity a ≈ concentration c (in mol/L) times activity coefficient γ (≈1 for dilute ideal solutions): a = γc/c°, with c° = 1 M.

    Corrected Statements

    Statement Verdict Reason
    I: μ_s = μ°_s + RT ln a True Standard form for solutes 
    II: μ°_s at 1 M False Defined at a=1 (hypothetical ideal state at 1 M reference) 

    Applications

    Used in osmosis (solute μ gradients draw water), biochemistry (enzyme-substrate binding), and colligative properties. Real solutions adjust via γ to approach ideality.

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